Ben meets his favorite superhero idol Captain Nemesis when he shows up to save actress Jennifer Nocturne, however Captain Nemesis is displeased when Ben gets kissed by the actress instead of him. Captain Nemesis' assistant, Simons meets up with Will Harangue about staging an event that will put Captain Nemesis back on the front page of each magazine. When Ben wins, The Captain goes to extreme lengths to prove everyone that he is the best superhero of all time. He captures Julie and Jennifer and Ben tries to call Julie to go to Mr. Smoothy's he gets a message from Captain Nemesis telling Ben to try and save her. Ben goes to rescue Julie and Jennifer by going ultimate Humongosaur and uses goop to rescue Julie. Kevin and Gwen rescue Jennifer and Jennifer loves Kevin. Ben defeats Captain Nemesis with Water Hazard and Captain Nemesis gets arrested. But when Jennifer falls in love with Kevin, Gwen threatens her to get her away from Kevin.
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